Oxyalkylated polyol prepolymers, flame retardant...

C - Chemistry – Metallurgy – 08 – G

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403/36, 402/43,

C08G 18/12 (2006.01) C08G 8/08 (2006.01) C08G 16/02 (2006.01) C08G 16/04 (2006.01) C08G 18/54 (2006.01)

Patent

CA 1123989

ABSTRACT OF THE DISCLOSURE: Liquid oxyalkylated polyol prepolymers are prepared by oxyalkylating a propolymer prepared from a hydroxy aromatic compound, an aldehyde and furfuryl alcohol with an alkylene oxide containing about 2-4 carbon atoms The oxyalkylated polyol prepolymers have a viscosity of 1000-500,000 centipoises at 25°C. and contain about 1.1-6 moles of interpolymerized aldehyde, about 3.1-15 moles of interpolymerized furfuryl alcohol, and about 1-10 moles of interpolymerized alkylene oxide for each moe of interpolymerized hydroxy aromatic compound. The resultant prepolymers are highly reactive and may be further polymerized with or without monomers such as polyisocyanate to produce flame retardant solid or cel- lular interpolymers. Flame retardant solid or cellular poly- urethanes are prepared in one variant by interpolymerized organic polyisocyanates with the oxyalkylated polyol pre- polymers. In another variant, flame retardant closed cell cellular interpolymers are provided. Processess are provided for preparing the aforementioned novel oxyalkylated polyol prepolymers and solid or cellular interpolymers.

291372

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