Oxygenate treatment of dewaxing catalyst for greater yield...

B - Operations – Transporting – 01 – J

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B01J 29/06 (2006.01) B01J 29/67 (2006.01) B01J 29/74 (2006.01) B01J 37/18 (2006.01) C10G 2/00 (2006.01) C10G 45/64 (2006.01) B01J 31/02 (2006.01)

Patent

CA 2498926

Fischer-Tropsch hydrocarbon synthesis using a cobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided 10-ring, 1-dimensional zeolite catalyst that has been reduced and then treated by contacting it with the synthesized hydrocarbons containing one or more oxygenates, including indigenous oxygenate. Tail gas from the hydrodewaxing reactor can be used for the hydrocarbon synthesis.

La synthèse Fischer-Tropsch des hydrocarbures au moyen d'un catalyseur au cobalt s'utilise pour produire des hydrocarbures à base paraffinique pour carburants et huiles de graissage à partir du gaz de synthèse tiré de gaz naturel. Les hydrocarbures à base paraffinique sont hydrodéparaffinés, avec transformation réduite en hydrocarbures à point d'ébullition plus faible, par mise en contact en présence d'hydrogène avec un catalyseur zéolitique unidimensionnel à cycle à 10 éléments sans sulfure qui a été réduit au contact d'hydrocarbures synthétisés renfermant un ou plusieurs produits oxygénés, indigènes notamment. Le gaz de queue du réacteur d'hydrodéparaffinage peut être utilisé pour la synthèse d'hydrocarbures.

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