Perfluoropolyoxyalkylene endowed with a high viscosity and a...

C - Chemistry – Metallurgy – 08 – F

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C08F 114/26 (2006.01) B01J 19/12 (2006.01) C07C 41/06 (2006.01) C08F 2/06 (2006.01) C08F 2/48 (2006.01) C08G 18/50 (2006.01) C08G 63/682 (2006.01) C08G 65/00 (2006.01)

Patent

CA 2067321

Peroxy perfluoropalyaxyalkylenes are prepared in relatively high yields by carrying out the photo-oxidation of tetrafluoroethylene with molecular oxygen, by means of ultraviolet radiation , operating in the presence of pentafluorochloroethane as a solvent for tetrafluoroethylene. Thus, it is possible to obtain peroxy perfluoropolyoxyalkylenes having a viscosity at 20°C ranging from 300,000 to 8,000,000 cSt and endowed with a peroxide content not higher than 4. Such perfluoropolyoxyalkylenes provide, through chemical reduction, perfluoropolyoxyalkylenes endowed with a functionality higher than 1.9 and at the same time with a high molecular weight:

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