Phosphorescent marine products

C - Chemistry – Metallurgy – 09 – K

Patent

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Details

C09K 11/64 (2006.01) B63B 35/00 (2006.01) B63B 45/04 (2006.01)

Patent

CA 2343938

In one embodiment of the invention, a marine article of the invention includes a phosphorescent phosphor. A particularly advantageous phosphorescent phosphor comprises MA12O4. As used herein, "M" is at least one cation selected from a group consisting of calcium, strontium, and barium. The phosphor comprises 0.001 % to 10 % of a europium activator, and 0.001 % to 10 % of at least one dopant selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, samarium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, tin and bismuth as a co-activator, in terms of mol % relative to the metal element expressed by M. The phosphorescent marine article has an afterglow corresponding to a luminance of at least 0.3 mCd/m2 for at least 420 minutes.

Dans un mode de réalisation, un produit marin selon l'invention comprend un comprend un phosphore phosphorescent, dont une forme -articulièrement avantageuse comprend MAl¿2?O¿4?, dans lequel, M représente au moins un cation choisi dans le groupe constitué de calcium, de strontium et de baryum. Le phosphore comprend, en termes de pourcentage en moles, de 0,001 % à 10 % d'un activateur à l'europium et de 0,001 % à 10 % d'au moins un dopant choisi dans le groupe constitué de lanthane, de cérium, de praséodyme, de néodyme, de samarium, de gadolinium, de dysprosium, de holmium, d'erbium, de thulium, d'ytterbium, de lutécium, d'étain et de bismuth en tant que co-activateur, par rapport à l'élément métallique représenté par M. Le produit marin selon l'invention présente une luminescence résiduelle s'élevant à au moins 0,3 mCd/m?2¿ pendant au moins 420 minutes.

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