B - Operations – Transporting – 01 – J
Patent
B - Operations, Transporting
01
J
252/95, 260/365.
B01J 27/198 (2006.01) C07C 51/145 (2006.01) C07C 51/215 (2006.01) C07C 51/25 (2006.01) C07C 51/31 (2006.01)
Patent
CA 1227784
PHOSPHORUS-VANADIUM-MIXED OXIDE OXIDATION CATALYSTS AND PROCESSES FOR THE PREPARATION AND USE THEREOF ABSTRACT OF THE DISCLOSURE Maleic anhydride is produced by the oxida- tion of a non-aromatic hydrocarbon having at least four carbon atoms in a straight chain with molecular oxygen or a molecular oxygen-containing gas in the vapor phase in the presence of a phosphorus-vanadium mixed oxide oxidation catalyst. Such catalysts are are prepared by introducing a substantially pentavalent vanadium-containing compound and a pentavalent phosphorus-containing compound into an alcohol medium capable of reducing the vanadium to a valence state less than +5 in the presence of an alcohol-modifying agent to form a phosphorus-vanadium mixed oxide catalyst precursor. The catalyst pre- cursor is recovered, dried, formed into desired structures, and calcined at temperatures from about 250° C to about 600° C. The catalysts are highly effective in that they exhibit a weight/weight productivity of at least 70 grams of maleic anhydride per kilogram of catalyst per hour.
469844
Edwards James W.
Graham Charles R.
Keppel Robert A.
Raffelson Harold
Wrobleski James T.
Mcfadden Fincham
Monsanto Company
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