Phosphorus-vanadium-mixed oxide oxidation catalysts and...

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B01J 27/198 (2006.01) C07C 51/145 (2006.01) C07C 51/215 (2006.01) C07C 51/25 (2006.01) C07C 51/31 (2006.01)

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CA 1227784

PHOSPHORUS-VANADIUM-MIXED OXIDE OXIDATION CATALYSTS AND PROCESSES FOR THE PREPARATION AND USE THEREOF ABSTRACT OF THE DISCLOSURE Maleic anhydride is produced by the oxida- tion of a non-aromatic hydrocarbon having at least four carbon atoms in a straight chain with molecular oxygen or a molecular oxygen-containing gas in the vapor phase in the presence of a phosphorus-vanadium mixed oxide oxidation catalyst. Such catalysts are are prepared by introducing a substantially pentavalent vanadium-containing compound and a pentavalent phosphorus-containing compound into an alcohol medium capable of reducing the vanadium to a valence state less than +5 in the presence of an alcohol-modifying agent to form a phosphorus-vanadium mixed oxide catalyst precursor. The catalyst pre- cursor is recovered, dried, formed into desired structures, and calcined at temperatures from about 250° C to about 600° C. The catalysts are highly effective in that they exhibit a weight/weight productivity of at least 70 grams of maleic anhydride per kilogram of catalyst per hour.

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