Photoresists formed by polymerization of di-unsaturated...

G - Physics – 03 – F

Patent

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G03F 7/028 (2006.01) C23C 16/02 (2006.01) G03F 7/027 (2006.01) G03F 7/038 (2006.01) G03F 7/039 (2006.01) G03F 7/16 (2006.01) H01C 17/08 (2006.01) H01C 17/24 (2006.01)

Patent

CA 2019666

ABSTRACT PHOTORESISTS FORMED BY POLYMERISATION OF DI-UNSATURATED MONOMERS A photoresist coating for use in microlithography comprises a polymer of a monomer of the formula Image V wherein X and Y are strong electron withdrawing groups and R4 is H or, providing that X and Y are both -CN, R4 may be aliphatic hydrocarbyl, aryl or alkaryl. Preferred monomers are of the formula Image Va wherein R7 is a C1-C5 alkyl or C2-C5 alkenyl group, more particularly ethyl 2-cyanopenta-2,4-dienoate or allyl 2-cyanopenta-2,4- dienoate. Methods for applying a resist coating by vapour deposition of these monomers and exposure to radiation are described. A positive or negative tone image can be produced, depending upon the imaging method employed. - 17 -

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