Phthalocyanine photosensitizers for photodynamic therapy and...

C - Chemistry – Metallurgy – 09 – B

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C09B 47/08 (2006.01) A61K 31/695 (2006.01) C07F 7/08 (2006.01) C07F 7/18 (2006.01) C09B 47/04 (2006.01)

Patent

CA 2086942

2086942 9201753 PCTABS00010 The present invention relates to a series of novel phthalocyanine compositions (or compounds) suitable for use as photosensitizers for photodynamic therapy. Specifically, the invention relates to a series of new aluminum (Al) and/or silicon (Si) phthalocyanines having substituted amine or quaternary ammonium axial ligands attached to the central metal, and the use of these new phthalocyanine compositions for the treatment of cancer through photosensitization. Moreover, the present invention is directed to the methods of preparing these compositions for use in photodynamic therapy. The phthalocyanine compounds have formula (I), wherein M = AlOSi(CH3)2(CH2)3N(CH3)2; AlOSi(CH3)2(CH2)3N(CH3)3+I-; HOSiOSi(CH3)2(CH2)3N(CH3)2, or HOSiOSi(CH3)2(CH2)3N(CH3)3+I-.

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