Physical and mechanical properties of pea starch edible...

C - Chemistry – Metallurgy – 08 – L

Patent

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C08L 3/12 (2006.01) B65D 65/46 (2006.01) C08J 5/18 (2006.01) C08L 91/00 (2006.01)

Patent

CA 2656293

Hydrophobic beeswax emulsions were incorporated into hydrophilic starch films to modify physical, mechanical and thermal properties of the films. Beeswax was added in the film-forming solution of high amylose pea starch (35 - 40% amylose w/w) at the level of 0, 10, 20, 30 and 40% w/w of starch with glycerol as a plasticizer (40/60 of glycerol/starch). Addition of beeswax affected mechanical properties significantly reducing tensile strength and elongation, and increasing elastic modulus. Beeswax addition decreased water vapor permeability, and increased oxygen permeability. However, the addition of hydrophobic wax particles in starch films marginally affected these physical properties below 30% beeswax in the films. Beeswax addition at the 40% concentration formed amylose-lipid complex which caused the dramatic changes of physical and thermal properties of the films

Cette invention se rapporte à des émulsions de cire d'abeille hydrophobes qui ont été incorporées dans des films d'amidon hydrophiles pour modifier les propriétés physiques, mécaniques et thermiques de ces films. La cire d'abeille a été ajoutée dans une solution filmogène d'amidon de pois à teneur élevée en amylose (35 - 40 % d'amylose p/p) au taux de 0, 10, 20, 30 et 40 % p/p d'amidon avec un glycérol comme plastifiant (40/60 de glycérol/amidon). L'addition de cire d'abeille a eu une incidence sur les propriétés mécaniques, réduisant de façon significative la résistance à la traction et l'allongement et augmentant le module élastique. L'addition de cire d'abeille a diminué la perméabilité à la vapeur d'eau et a augmenté la perméabilité à l'oxygène. Cependant, l'addition de particules de cire hydrophobes dans les films d'amidon a modifié de façon marginale ces propriétés physiques au-dessous de 30 % de cire d'abeille dans les films. L'addition de cire d'abeille à une concentration de 40 % a permis de former un complexe amylose-lipide qui a entraînés des changements spectaculaires des propriétés physiques et thermiques des films.

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