Poly-alkylated benzodioxin musk compositions

C - Chemistry – Metallurgy – 07 – C

Patent

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167/321, 260/621

C07C 39/06 (2006.01) C07C 39/11 (2006.01) C07D 319/08 (2006.01) C11B 9/00 (2006.01)

Patent

CA 2008976

ABSTRACT The present invention relates to novel poly-alkylated benzodioxin compounds possessing a musk-like aroma which are useful as fragrance materials. The compounds of the invention have the formula: Image . where R1 to R4 are hydrogen or lower alkyl (C1 to C5), provided that the compound has no more than 18 carbon atoms. The invention provides for synthesis of a novel phenolic intermediate and synthesis of the compounds of the invention. The invention also provides fragrance compositions which utilize the compounds of the invention to modify, enhance, or impart a musk-like aroma to perfume compositions, colognes and perfumed articles.

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