Polyadducts of ammonia and epoxide compounds, processes for...

C - Chemistry – Metallurgy – 08 – G

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402/2, 402/268,

C08G 59/40 (2006.01) C08G 12/00 (2006.01) C08G 12/02 (2006.01) C08G 12/46 (2006.01) C08G 59/14 (2006.01) C08G 65/26 (2006.01) C09D 5/44 (2006.01)

Patent

CA 1180493

Abstract of the Disclosure: Polyadducts, free from epoxide groups, are obtained from ammonia and epoxide compounds by reacting 1 mole of ammonia with from 1.2 to 2.0 equivalents of epoxide, so that if diepoxide com- pounds are used products of the general formula (I) Image are obtained, whilst if triepoxides and/or tetraepoxide compounds are used, by themselves, or together with diepoxide compounds, products of the general formula II Image (II) are produced; in these formulae, the E1's are identical or different hydroxyl-containing divalent radicals and the E2's are identical or different hydroxyl-containing trivalent or tetravalent radicals, resulting from the opening of the oxirane rings of epoxide compounds con- taining two, three or four epoxide groups in the mole- cule, n1, n3 and n5 are from 0 to 3, n2 and n4 are from 1 to 3 and X is 0 or 1, and one or more of the divalent radicals E1 in the general formula (II) may or may not - 1 - be replaced by polyvalent radicals E2. The novel polyadducts can be modified by reaction with aldehydes, ketones, monoepoxide compounds, carboxy- lic acids, carboxylic acid esters or isocyanates, or by protonation with an acid, and may be used, for example, for the cathodic electrocoating of metallic articles.

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