Polyalcoxylated terpenic compounds, method of preparation...

C - Chemistry – Metallurgy – 07 – C

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C07C 43/178 (2006.01) B01D 19/04 (2006.01) C07C 43/196 (2006.01) C08G 65/26 (2006.01) C08G 65/329 (2006.01) C11D 1/72 (2006.01) C11D 1/722 (2006.01) C11D 3/00 (2006.01)

Patent

CA 2275363

The invention concerns polyalcoxylated terpenic compounds of formula Z-X-W-[CH(R<5>)-CH(R<6>)-O]q-A in which Z is a bicycloheptenyl or bicycloheptyl radical, preferably substituted by methyl radicals; X is preferably a -CH2-CH2-O or -O-CH2-CH2-O- radical; W is a polysequence, preferably polyoxypropylene and polyoxyethylene; [CH(R<5>)-CH(R<6>)-O]q is a sequence different from a polyoxyethylene sequence, preferably polyoxypropylene; A is H, a functional or hydrocarbon group. They can be prepared by successively polyalcoxylating the reagent Z-XH. They can be used as antifoaming agents in foaming aqueous media, in particular in degreasing aqueous media in alkaline medium of sheet metals, as well as detergent aqueous media in household washing or industrial and institutional washing.

Composés d'origine terpénique polyalcoxylés de formule Z-X-W-[CH(R5)-CH(R6)- O]q-A où Z est un radical bicycloheptényle ou bicycloheptyle, de préférence substitué par des radicaux méthyles X est de préférence un radical -CH2-CH2-O- ou -O-CH2-CH2-O-, W est une polyséquence, de préférence polyoxypropylénée et polyoxyéthylénée [CH(R5)-CH(R6)-O]q est une séquence différente d'une séquence polyoxyéthylénée, de préférence polyoxypropylénée A est H, un groupe hydrocarboné ou fonctionnel. Ils peuvent être préparés par polyalcoxylations successives du réactif Z-XH. Ils peuvent être utilisés comme agents démoussants des milieux aqueux moussants, notamment des milieux aqueux de dégraissage en milieu alcalin des tôles métalliques, ainsi que des milieux aqueux détergents utilisés en détergence ménagère ou en détergence industrielle et institutionnelle.

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