Polyalkoxysilylalkylenedisilazanes and silylamines

C - Chemistry – Metallurgy – 07 – F

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402/15, 260/445.

C07F 7/08 (2006.01) C07F 7/18 (2006.01) C08G 77/38 (2006.01) C08G 77/50 (2006.01) C08L 83/14 (2006.01)

Patent

CA 1331011

POLYALKOXYSILYLALKYLENEDISILAZANES AND SILYLAMINES Abstract A polyalkoxysilylalkylenedisilazane of the formula Image and a polyalkoxysilylalkylenesilylamine of the formula Image where x is 0 or 1; R is a saturated alkyl or aryl radical or a mixture of said radicals; R' is an alkyl, aryl, or 2-ethoxyethanol radical, or a mixture of said radicals; R'' is hydrogen, alkyl aryl, or a mixture of said radicals; and A is a divalent hydrocarbon radical having 2 to 20 carbon atoms; and a method for their manufacture by the platinum catalyzed addition of an alkenyl-functional disilazane or silylamine with an alkoxy-functional silicon hydride is disclosed. The silylamine can also be produced by the platinum catalyzed addition of a SiH functional silazane or silylamine and an alkenyltrialkoxysilane. The polyalkoxysilylalkylenedi- silazane and the polyalkoxysilylalkylenesilylamine can be reacted with a silanol containing polyorganosiloxane such as a hydroxyl endblocked polydiorganosiloxane in the presence of an acidic catalyst to give a polyalkoxysilyl terminated polydiorganosiloxane in which the terminal groups are bonded to the polymer through an alkylene linkage.

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