Polyamic acids dope composition, preparation method of...

D - Textiles – Paper – 01 – F

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D01F 1/08 (2006.01) C08L 77/10 (2006.01) C08L 79/08 (2006.01) D01D 5/24 (2006.01) D01F 6/60 (2006.01) D01F 6/74 (2006.01) D01F 11/08 (2006.01)

Patent

CA 2640517

Disclosed herein are a polyamic acid dope solution composition, a method for preparing a hollow fiber using the composition and a hollow fiber prepared by the method. More specifically, disclosed are a method for preparing a hollow fiber, comprising preparing a polyamic acid dope solution composition comprising polyhydroxyamic acid, polythiolamic acid or polyaminoamic acid, spinning the composition to prepare a hollow fiber, and imidizing and thermally rearranging the hollow fiber, and the hollow fiber prepared by the method. In accordance with the method, a hollow fiber made of a high free volume polymer membrane can be prepared by spinning the dope solution composition to prepare a hollow fiber and thermally rearranging the hollow fiber via thermal treatment. The hollow fiber thus prepared exhibits excellent gas permeability and selectivity, thus being suitable for use as a gas separation membrane.

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