Polyaminoacids functionalized by alpha tocopherol and uses...

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

C08G 69/10 (2006.01) A61K 9/51 (2006.01) A61K 47/34 (2006.01) A61K 47/42 (2006.01) C08G 69/48 (2006.01)

Patent

CA 2486944

The invention concerns novel biodegradable polyaminoacid materials, useful in particular for vectoring active principle(s). The invention also concerns novel pharmaceutical, cosmetic, dietetic or phytosanitary compositions based on said polyaminoacids. The invention aims at providing a novel polymer raw material, capable of being used for vectoring active principles and enabling optimal fulfillment of all specified requirements: biocompatibility, biodegradability, easy and inexpensive transformation into particles vectoring active principles, said particles being themselves capable of forming colloidal suspensions, of being easily associated with numerous active principles, and of releasing said active principles in vivo. Therefor, the present invention concerns first of all amphiphilic polyaminoacids comprising aspartic acid units and/or glutamic acid units, characterized in that at least part of said units carry grafts including at least one alpha-tocopherol motif, for example (polyglutamate or polyaspartate grafted with alpha-tocopherol of synthetic or natural origin).

La présente invention concerne des nouveaux matériaux à base de polyaminoacide5 biodégradables, utiles notamment pour la vectorisation de principe(s) actif(s) (PA) L'invention vise aussi de nouvelles compositions pharmaceutiques, cosmétiques diététiques ou phytosanitaires à base de ces polyaminoacides. Le but de l'invention est de fournir une nouvelle matière première polymère, susceptible d'être utilisée pour la vectorisation de PA et permettant de satisfaire de manière optimale à toutes les spécifications du cahier des charges : biocompatibilité, biodégradabilité, aptitude à se transformer aisément et économiquement en particules de vectorisation de principes actifs, ces particules étant elles même propres à former des suspensions colloïdales aqueuses stables, à s'associer facilement avec de nombreux principes actifs, et à libérer ces principes actifs in vivo. Ce but est atteint par la présente invention qui concerne tout d'abord des polyaminoacides amphiphiles comprenant des unités aspartique et/ou des unités glutamiques, caractérisés en ce qu'au moins une partie de ces unités sont porteuses de greffons comportant au moins un motif alpha-tocophérol, e.g. : (polyglutamate ou polyaspartate greffé par l'alpha tocophérol d'origine synthétique ou naturelle).

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