Polyester compositions, methods of manufacturing said...

C - Chemistry – Metallurgy – 08 – G

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C08G 63/12 (2006.01) A61L 31/06 (2006.01) A61L 31/14 (2006.01)

Patent

CA 2663637

Crosslinked polymer compositions have backbones with first and second divalent saturated aliphatic moieties, a divalent saturated aliphatic secondary alcohol moiety, and a trivalent saturated aliphatic moiety. Hydrolytically labile ester bonds joined together these moieties. These polyesters may be polycondensation reaction products of a diol, a triol and a diacid. A molar ratio of the first divalent saturated aliphatic moiety, the divalent saturated aliphatic secondary alcohol moiety, and the trivalent saturated aliphatic moiety to the second divalent saturated aliphatic moiety is in the range of about 0.85 to about 1.5. Preferably, these polyesters are non-cytotoxic, biocompatible, bioabsorbable, or exhibit shape memory behavior with at least one transition temperature of greater than about 30 0C and less than about 100 0C and most preferably exhibit each of these qualities. The compositions may be adapted for a wide variety of uses, including medical applications.

La présente invention concerne des compositions de polymère réticulé qui ont des squelettes avec un premier et un second groupement aliphatique saturé divalent, un groupement alcool secondaire aliphatique saturé divalent, et un groupement aliphatique saturé trivalent. Des liaisons ester labiles de manière hydrolytique ont relié ensemble ces groupements. Ces polyesters peuvent être des produits de la réaction de polycondensation d'un diol, d'un triol et d'un diacide. Un rapport molaire du premier groupement aliphatique saturé divalent, du groupement alcool secondaire aliphatique saturé divalent, et du groupement aliphatique saturé trivalent sur le second groupement aliphatique saturé divalent est dans la plage d'environ 0,85 à environ 1,5. De préférence, ces polyesters sont non cytotoxiques, biocompatibles, bioabsorbables, ou présentent un comportement à mémoire de forme avec au moins une température de transition supérieure à environ 30 °C et inférieure à environ 100 °C et, idéalement, présentent chacune de ces qualités. Les compositions peuvent être adaptées pour une large variété d'utilisations, y compris des applications médicales.

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