Polyethers obtainable by reacting alkylolated bis-(4-...

C - Chemistry – Metallurgy – 08 – G

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402/43, 134/56

C08G 65/32 (2006.01) C08G 8/36 (2006.01) C08G 65/34 (2006.01) C08G 81/00 (2006.01) C10G 33/04 (2006.01)

Patent

CA 1282897

Abstract of the Disclosure: Polyethers with are suitable as oil demulsifiers are obtainable by reacting A) a polyalkylene oxide obtained from ethylene oxide and propylene oxide and containing in total from 5 to 200 alkylene oxide units with B) an alkylolation product of a low molecular weight alde- hyde and a bis-(4-hydroxyphenyl)-methane of the general formula II Image where R1 and R2 may be identical or different and are each hydrogen, low molecular weight alkyl, phenyl, carboxyl or low molecular weight alkoxycarbonyl, the molar reaction ratio of the compound of the formula II to the alkylolat- ing aldehyde being from 1:1 to 1:4, at from 100 to 180°C in the presence of an acidic cata- lyst with removal of the water of reaction, the weight ratio of A to B being from 5:1 to 1:3.

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