Polyfunctional biocompatible hydrogel and method for the...

A - Human Necessities – 61 – K

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A61K 47/32 (2006.01) C08F 2/10 (2006.01) C08F 220/56 (2006.01)

Patent

CA 2452442

The inventive polyfunctional biocompatible hydrogel comprises 1.95-8.0 mass % of acrylamide, 0.54-3.0 mass% of methacrylamide, 0.003-0.4 mass% of 2- hydroxyethyl methacrylate, 0.006-0.6 mass% of N,N'-methylen-bis-acrylamide, and water up to 100 mass%. The hydrogel is produced by copolymerising said monomers in an aqueous medium in the presence of a peroxide polymerisation initiator, the incubation of a reaction mixture being carried out in three stages. The first stage is carried out at a temperature ranging from 20 to 30~C during a time of 12 to 24 hours, the second stage is carried out by irradiating with .gamma.-radiation dose of 0.4 to 1.0 megarad, the third stage being carried out at a temperature ranging from 100 to 130~C and a pressure of 0 to 1.2 atm. during a time of 20 to 40 minutes.

L'hydrogel biocompatible multifonctions de l'invention comprend, en % en masse, 1,95-8,0 d'acrylamide, 0,54-3,0 de méthacrylamide, 0,003-0,4 de 2-hydroxyéthyl méthacrylate, 0,006-0,6 de N,N'-méthylen-bis-acrylamide et jusqu'à 100 % en masse d'eau. L'hydrogel est produit par copolymérisation desdits monomères dans un milieu liquide en présence d'un initiateur peroxyde de polymérisation, l'incubation du mélange de réaction se faisant en trois stades, le premier stade étant mis en oeuvre à une température de 20 à 30 ·C durant 12 à 24 h, le deuxième stade comprenant l'irradiation .gamma. avec une dose de 0,4 à 1,0, et le troisième stade étant réalisé à une température entre 100 et 130 ·C et à une pression de 0 à 1,2 atm pendant 20 à 40 minutes.

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