Polyhexamethylene adipamide fiber having high dimensional...

D - Textiles – Paper – 01 – F

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D01F 6/60 (2006.01) D02J 1/22 (2006.01)

Patent

CA 1235269

POLYHEXAMETHYLENE ADIPAMIDE FIBER HAVING HIGH DIMENSIONAL STABILITY AND HIGH FATIGUE RESISTANCE, AND PROCESS FOR PREPARATION THEREOF ABSTRACT OF THE DISCLOSURE A high-tenacity polyhexamethylene adipamide fiber is described, which has (1) a formic acid relative viscosity of 50 to 150, (2) a tensile strength of at least 7.5 g/d, (3) an intermediate elongation not larger than 8% under 5.3 g/d, (4) a difference between elon- gation (%) at break and intermediate elongation (%) under 5.3 g/d of at least 6%, and (5) a shrinkage factor not larger than 5% under dry heat conditions at 160°C. Preferably, the fiber has (6) an elongation of 12 to 20%, (7) a dimensional stability not larger than 13%, (8) a crystal orientation degree of at least 0.85 but not larger than 0.92, (9) a crystal perfection index of at least 60%, and (10) the peak temperature Tmax of the dynamic mechanical loss tangent (tan .delta.), as measured at a frequency of 110 Hz, satisfying the formula: 100 ? Tmax + 4(9.5 - DS) ? 116 wherein DS is for the tensile strength (g/d). This fiber is prepared by melting polyhexamethylene adipamide having a formic acid relative viscosity of 50 to 150, extruding the melt from a spinneret, cooling the extrudate to be thereby solidified, winding the resulting filament yarn at a take-up speed of 1000 to 6000 m/min, and then heat-drawing the filament yarn at a drawing speed not higher than 100 m/min.

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