Polyhydroxyalkanotes and film formation therefrom

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 63/06 (2006.01) C08J 5/18 (2006.01)

Patent

CA 2153807

A supported or cast film of a polyhydroxyalkanoate polymer, such as a polyhydroxybuxyrate/valerate polymer, can be prepared by applying a layer of molten polymer to a cool (typically 4 to 20 °C) surface not substantially above the glass transition temperature of the polymer, so as to form a solid, glassy film with a high density of nucleation sites; subsequently the temperature of the film so formed is raised, for example to 40 °C or more, towards the optimum temperature for growth of the polymer's spherulites effectively separating the film formation/nucleation step from the crystallisation step (growth of spherulites around the nucleation sites). Smaller crystallites are formed, and the film has improved barrier properties.

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