Polyimides dope composition, preparation method of hollow...

D - Textiles – Paper – 01 – F

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D01F 1/08 (2006.01) B01D 69/08 (2006.01) C08L 79/08 (2006.01) D01D 5/24 (2006.01) D01F 6/74 (2006.01) D01F 11/08 (2006.01)

Patent

CA 2640545

Disclosed herein are a polyimide dope solution composition, a method for preparing a hollow fiber using the composition and a hollow fiber prepared by the method. More specifically, disclosed are a method for preparing a hollow fiber, comprising preparing a polyimide dope solution composition comprising polyhydroxyimide, polythiolimide or polyaminoimide, spinning the composition to prepare a hollow fiber, and thermally rearranging the hollow fiber, and the hollow fiber prepared by the method. In accordance with the method, a hollow fiber made of a high free volume polymer membrane can be prepared by spinning the dope solution composition to prepare a hollow fiber and thermally rearranging the hollow fiber via thermal treatment. The hollow fiber thus prepared exhibits excellent gas permeability and selectivity, thus being suitable for use as a gas separation membrane.

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