Polyimides, polyamic acid and ester intermediates thereof,...

C - Chemistry – Metallurgy – 08 – G

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402/220, 154/107

C08G 73/10 (2006.01)

Patent

CA 1219398

NOVEL POLYIMIDES, POLYAMIC ACID AND ESTER INTERMEDIATES THEREOF, AND NOVEL AROMATIC DIAMINES FOR THEIR PREPARATION ABSTRACT OF THE DISCLOSURE Novel polyimides, optionally end-capped with polymerizable or inert groups, and the polyamic acid or ester intermediates thereof are prepared by reacting a tetracarboxylic acid compound (e.g. pyromellitic dianhydride or 3,3',4,4'-benzophenone tetracarboxylic acid dianhydride or its methyl diester) with diamines having the general formula Image , wherein Z is oxygen or sulfur, X and/or Y are carbonyl or carbinol groups, the amine groups may be in the 2-, 3-, and/or 4-position, and isomerism is present when X and/or Y is d carbinol group. The polyi- mides may be end-capped by reaction, during or after their formation, with polymerizable groups such as 3-aminophenyl acetylene or 3,6-endo- methylene-1,2,3,6-tetrahydrophthalic anhydride. The diamines are novel classes of amines when Z is sulfur and when Z is oxygen and X, Y, or X and Y are carbinol groups.

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