Polyisocyanate mixtures, a process for their production and...

C - Chemistry – Metallurgy – 07 – C

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C07C 271/08 (2006.01) C07C 265/04 (2006.01) C07C 265/10 (2006.01) C07C 271/10 (2006.01) C07C 271/24 (2006.01) C07D 251/34 (2006.01) C08G 18/02 (2006.01) C08G 18/72 (2006.01) C09D 175/04 (2006.01)

Patent

CA 2110236

POLYISOCYANATE MIXTURES, A PROCESS FOR THEIR PRODUCTION AND THEIR USE FOR THE PRODUCTION OF POLYURETHANES ABSTRACT OF THE DISCLOSURE The present invention relates to polyisocyanate mixtures which are solid below 40°C and liquid above 125°C and which have a) an average isocyanate functionality of at least 2.1, b) a content of free isocyanate groups bonded to tertiary (cyclo)aliphatic carbon atoms (calculated as NCO; molecular weight = 42) of 5 to 22 wt.%, c) a urethane group content calculated as -NH-CO-O-; molecular weight = 59) of 2 to 30 wt.%, d) an isocyanate group content (calculated as C3N3O3; molecular weight = 126) of 0 to 30 wt.% and e) a carboxylic acid ester group content (calculated as -CO-O-; molecular weight= 44) of 0 to 25 wt.% and/or f) a carbonate group content (calculated as -O-CO-O-; molecular weight = 60) of from 0 to 34wt.% with the proviso that the total amount of ester groups e) and carbonate groups f) is at least 2 wt.%. The present invention also relates to a process for the production of these polyisocyanate mixtures and to their use for the production of polyurethanes, inparticular as the crosslinking component in heat-curable two-component poly- urethane powder coatings for coating heat-resistant substrates.

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