Polyisocyanates with biuret structure, blocked with...

C - Chemistry – Metallurgy – 08 – G

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C08G 18/80 (2006.01) C07B 61/00 (2006.01) C07C 211/02 (2006.01) C07C 263/18 (2006.01) C07C 265/14 (2006.01) C07C 275/00 (2006.01) C07C 275/62 (2006.01) C08G 18/00 (2006.01) C08G 18/32 (2006.01) C08G 18/78 (2006.01) C08J 7/04 (2006.01) C09D 175/04 (2006.01) C09D 175/12 (2006.01)

Patent

CA 2485156

Storage-stable blocked polyisocyanates prepared by reacting one or more polyisocyanates with one or more biuretizing agents and optionally, catalysts such that in the blocked end product there are 5-45 equivalent percent of biuret groups according to formula (I) (see formula I) based on the sum total of all free and blocked NCO groups; optionally modifying the resulting biuret polyisocyanates with the aid of isocyanate-reactive compounds and/or catalysts, with further reaction of free NCO groups; and subsequently blocking at least 95 mol percent of the remaining free NCO groups with a blocking agent according to the formula R1R2NH, where R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals. The blocked polyisocyanates can be used to make polyurethane polymers and coating compositions, which can be used to coat substrates.

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