Polymer bead containing immobilized metal extractant

C - Chemistry – Metallurgy – 12 – N

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C12N 11/12 (2006.01) B01J 13/02 (2006.01) B01J 13/06 (2006.01) B01J 20/24 (2006.01) B01J 20/26 (2006.01) B01J 20/28 (2006.01) B01J 20/32 (2006.01) C02F 1/26 (2006.01) C02F 1/28 (2006.01) C02F 1/52 (2006.01) C12N 11/04 (2006.01) C12N 11/08 (2006.01) C22B 3/18 (2006.01)

Patent

CA 2044167

Toxic metal contaminants dissolved in dilute aqueous solutions such as waste waters are removed by contact with water in- soluble polymeric beads having an internal pore structure containing immobilized extractant material capable of sorbing the me- tal contaminants. The beads are prepared by forming a solution of a polymeric material in an organic solvent, blending the ex- tractant into the solution and injection the solution through a nozzle into water to form beads. The polymeric material is preferably polysulfone or cellulose acetate, and the extractant may be yeast, algae, penicillium mold, xanthan gum, guar gum, al- ginate, common duckweed (Lemna sp.) or a chemical compound. A metal of value can be separated from the extractant by using dilute mineral acids or other dilute solutions to solubilize the metal.

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