Polymeric hydridochlorosilazanes, process for their...

C - Chemistry – Metallurgy – 08 – G

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402/10, 261/41

C08G 77/54 (2006.01) C04B 35/14 (2006.01) C04B 35/589 (2006.01) C08G 77/62 (2006.01)

Patent

CA 2004399

HOE 88/F 340 ABSTRACT OF THE DISCLOSURE: Polymeric hydridochlorosilazanes, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manu- facture The invention relates to novel polymeric hydridochloro- silazanes, to their preparation, to their processing to form ceramic materials containing silicon nitride, and to said materials themselves. The polymeric hydridochloro- silazanes are prepared by reacting oligohydridoorgano- silazanes of the general formula (R1SiHNH)n, in which n is about 3 to about 12, with at least one of the chloro- silanes R2SiHCl2, R3SiCl3, Cl2R4Si-CH2CH2-SiR4Cl2 or Cl3Si-CH2CH2-SiR5Cl2 at 30°C to 300°C, where the radicals independently of one another have the following meanings: R1 = a C1-C6 alkyl or C2-C6 alkenyl group, R2 = a C2-C6 alkenyl group if R2SiHCl2 is reacted with the oligosilazanes by itself, or R2 = a C1-C6 alkyl or C2-C6 alkenyl group if R2SiHCl2 is reacted with the oligosilazanes as a mixture with other chlorosilanes, and R3, R4, R5 = a C1-C6 alkyl or C2-C6 alkenyl group, and where R3SiCl3 is used only as a mixture with at least one of the other chorosilanes (containing R2, R4 or R5). The polymeric hydridochlorosilazanes according to the invention can be converted into polysilazanes by reaction with ammonia, and these in turn can be pyrolyzed to form ceramic materials containing silicon nitride.

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