Polymerisation catalyst

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 4/64 (2006.01) C08F 4/78 (2006.01) C08F 10/00 (2006.01) C08F 10/02 (2006.01) C08F 210/00 (2006.01)

Patent

CA 1194015

ABSTRACT OF THE DISCLOSURE A modified catalyst suitable for polymerizing 1-olefins prepared by (1) heat-activating a Phillips chromium oxide/ refractory oxide catalyst and (2) contacting the active catalyst with a titanium compound containing at least one pi-bonded ligand. The pi-bonded ligand can be an arene (e.g. benzene), a cyclic carbanion (e.g. cyclopentadienyl) or a cyclic carbonium ion (e.g. cycloheptatrienyl). Titanium (0) ditoluene is preferred. The catalyst can be used to (co)polymerize ethylene to give polyolefins having medium to broad molecular weight distribution.

422010

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