C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
252/100, 402/584
C08F 4/64 (2006.01) C08F 4/78 (2006.01) C08F 10/00 (2006.01) C08F 10/02 (2006.01) C08F 210/00 (2006.01)
Patent
CA 1194015
ABSTRACT OF THE DISCLOSURE A modified catalyst suitable for polymerizing 1-olefins prepared by (1) heat-activating a Phillips chromium oxide/ refractory oxide catalyst and (2) contacting the active catalyst with a titanium compound containing at least one pi-bonded ligand. The pi-bonded ligand can be an arene (e.g. benzene), a cyclic carbanion (e.g. cyclopentadienyl) or a cyclic carbonium ion (e.g. cycloheptatrienyl). Titanium (0) ditoluene is preferred. The catalyst can be used to (co)polymerize ethylene to give polyolefins having medium to broad molecular weight distribution.
422010
Bp Chemicals Limited
Fetherstonhaugh & Co.
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