Polymerisation process

C - Chemistry – Metallurgy – 08 – F

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C08F 210/02 (2006.01) C08F 4/642 (2006.01) C08F 4/76 (2006.01) C08F 10/00 (2006.01) C08F 210/16 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 2146208

A process for preparing bimodal molecular weight distribution copolymers of ethylene with alpha-olefins having 3 to 20 carbon atoms, said copolymers having: - (a) a comonomer distribution wherein the comonomer level at the mid-position of the low molecular weight component is <3 times the level at the mid-position of the high molecular weight component, and (b) a total average comonomer content in the range 0.5-20 short chain branches (SCB)/1000 C atoms characterised in that said process is carried out in the presence of a supported multisite catalyst. The multisite catalyst comprises a metallocene complex and a Ziegler catalyst. The metallocene complex for example is bis(pentamethylcyclopentadienyl) zirconium dichloride.

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