Polymerizable acrylic compositions having vinyl ether additives

C - Chemistry – Metallurgy – 08 – F

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C08F 4/82 (2006.01) C08F 4/40 (2006.01) C08F 216/12 (2006.01) C08F 220/10 (2006.01) C08F 224/00 (2006.01) C08F 283/00 (2006.01) C08F 283/06 (2006.01) C08F 299/00 (2006.01) C09J 5/00 (2006.01)

Patent

CA 1250082

ABSTRACT OF THE DISCLOSURE Polymerization of acid activated compositions of acrylic monomers, peroxy initiators and ferrocene derivatives is inhibited by addition of 0.5-20% of a vinyl ether monomer. Bulk compositions activated by addition of a strong acid can be provided with a desired polymerization induction time directly related to the concentration of the vinyl ether. Compositions containing compounds which decompose to a strong acid upon exposure to actinic radiation, thereby activating polymerization, have increased shelf lives when vinyl ethers are included therein. The use of vinyl ether monomers having a functionality of two or more also provides increased adhesive bond strength after curing.

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