Polymerization of polydiorganosiloxane in the presence of...

C - Chemistry – Metallurgy – 08 – G

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400/7218

C08G 77/06 (2006.01) C08K 3/00 (2006.01) C08L 83/06 (2006.01)

Patent

CA 1246275

POLYMERIZATION OF POLYDIORGANOSILOXANE IN THE PRESENCE OF FILLER Abstract A method of polymerizing hydroxyl-endblocked polydiorganosiloxane in the presence of filler, including acidic fillers such as fumed silica, through the use of basic diorganosilanolate catalysts is disclosed. Preferred diorganosilanolates are tetra-n-butylphosphonium dimethyl- silanolate and potassium dimethylsilanolate. The silicone polymer-filler mixture produced is useful in silicone greases and elastomers. Methods of combining the silicone polymer-filler mixture with various curing agents to yield curable compositions are claimed.

447036

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