Polymerization process for cis-1,4-polybutadiene using...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/62 (2006.01) C08F 136/06 (2006.01)

Patent

CA 1144299

ABSTRACT OF THE DISCLOSURE Substantially gel-free cis-1,4-polybutadiene is produced by polymerizing butadiene in the presence of a catalyst comprising a mixture of a cobalt compound, at least one organoaluminum compound and water, the improve- ment being the use of a cycloalkane having 5 to 8 carbon atoms in the ring and from 0.1 to 2 percent of an alkyl substituted benzene as a polymerization regulator.

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