Polymerization processes

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 4/00 (2006.01) C08F 2/38 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2164032

A polymerization process comprising: heating a mixture comprised of a free radical initiator, a stable free radical agent, at least onepolymerizable monomer compound, and optionally a solvent, to form a polymer with a high monomer to polymer conversion and a narrow polydispersity, wherein said polymer is comprised of a covalently bound free radical initiator fragment at one end and a covalently bound stable free radical compound at the other end of the polymer, and wherein said stable free radical agent has high thermal, acidic, and photochemical stability.

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