Polyphenylene ether-polyester copolymers and compatibilized...

C - Chemistry – Metallurgy – 08 – G

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C08G 81/00 (2006.01) C08L 53/02 (2006.01) C08L 67/00 (2006.01) C08L 71/12 (2006.01)

Patent

CA 2082735

08CN08534 POLYPHENYLENE ETHER-POLYESTER COPOLYMERS AND COMPATIBILZED MOLDING COMPOSITIONS THEREOF Abstract of the Disclosure Copolymers of epoxytriazine-functionalized polyphenylene ethers with segmented, linear copolyesters having carboxy end groups exhibit useful properties and fluid utility as molding compositions and as compatibilizers for blends of the component polymers. Representative epoxytriazine-capped polyphenylene ethers may be prepared by reaction of a polyphenylene ether with an epoxychlorotriazine such as diglycidyl chlorocyanurate, n-butyl glycidyl cholorcyanurate or mesityl gltcidyl chlorocyanurate. Representative copolyesters are those characterized by recurring intralinear long chain ester units of formula: Image (I) wherein G represents a divalent organic moiety remaining after removal of terminal hydroxy groups from a poly (alkylene ether) glycol; and R represents a divalent organic moiety remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300; interrupted by short chain ester chain units of the formula:- Image (II) wherein R has the meaning previously ascribed to it and D represents a divalent organic moiety remaining after removal of terminal hydroxyl group from a diol having a molecular weight of less than 250.

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