C - Chemistry – Metallurgy – 25 – B
Patent
C - Chemistry, Metallurgy
25
B
C25B 3/12 (2006.01) C07D 233/54 (2006.01) C07D 235/22 (2006.01)
Patent
CA 2650609
The present invention relates to a process for preparing a porous metal organic framework containing at least one organic compound coordinated to at least one metal ion, which comprises the step of oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of the at least one organic compound, where the at least one organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived at least from one of the heterocycles selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens, where the ring system is unsubstituted or has one or more substituents selected independently from the group consisting of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl, where the substituents C1-6-alkyl and phenyl are unsubstituted or have one or more substituents selected independently from the group consisting of halogen, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl.
La présente invention concerne un procédé de fabrication d'un matériau de squelette métallo-organique poreux contenant au moins un composé organique coordonné à au moins un ion métallique, ledit procédé comprenant l'étape consistant à oxyder au moins une anode contenant un métal correspondant à ion ou aux métalliques dans un milieu réactionnel en présence du ou des composés organiques, le ou les composés organiques présentant un système cyclique mono-, bi- ou polycyclique, dérivant au moins d'un hétérocycle choisi dans le groupe comprenant pyrrole, alpha-pyridone et gamma-pyridone et comprenant au moins deux atomes d'azote cycliques, le système cyclique n'étant pas substitué ou présentant un ou plusieurs substituants indépendamment choisis dans le groupe comprenant halogène, C1-6 alkyle, phényle, NH2, NH(C1-6 alkyle), N(C1-6 alkyle)2, OH, Ophényle et OC1-6 alkyle, les substituants C1-6 alkyle et phényle n'étant pas substitués ou présentant un ou plusieurs substituants indépendamment choisis dans le groupe comprenant halogène, NH2, NH(C1-6 alkyle), N(C1-6 alkyle)2, OH, Ophényle et OC1-6 alkyle.
Mueller Ulrich
Richter Ingo
Schubert Markus
Basf Se
Borden Ladner Gervais Llp
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