Porous polymethylsilsesquioxane with adsorbent properties

C - Chemistry – Metallurgy – 08 – G

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C08G 77/06 (2006.01) A61K 8/891 (2006.01) C11D 3/37 (2006.01) C12N 11/08 (2006.01) C11D 3/386 (2006.01)

Patent

CA 2354163

The invention concerns a porous polymethylsilsesquioxane (PMS) having a specific surface area ranging between about 50 and 500 m?2¿/g, a porous volume ranging between about 0.1 and 0.8 cm?3¿/g, a monolayer volume ranging between about 10 and 60 cm?3¿/g, a pore radius less than 1 mn of 90 % of the pores and insoluble in water and organic solvents. The inventive PMS is prepared by precipitating a polymethylsiliconate of general formula (I) wherein n is an integer between about 20 and 100 and M is an alkaline or alkaline-earth metal or NH¿4??+¿.

La présente demande décrit un polyméthylsilsesquioxane (PMS) poreux ayant une surface spécifique comprise entre environ 50 et 500 m2/g, un volume poreux compris entre environ 0,1 et 0,8 cm3/g, un volume de monocouche compris entre environ 10 et 60 cm3/g, un rayon de pores inférieur à 1 nm de 90 % des pores et l'insolubilité dans l'eau et des solvants organiques. Le PMS de l'invention est préparé par précipitation d'un polyméthylsiliconate de formule générale (I) dans laquelle n est un nombre entier compris entre environ 20 et 100 et M est un métal alcalin ou alcalino-terreux ou NH4+.

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