Porous solid phosphoric acid catalyst system and process...

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B01J 27/16 (2006.01) B01J 27/182 (2006.01) B01J 35/10 (2006.01) C07C 2/18 (2006.01) C07C 2/62 (2006.01) C07C 2/70 (2006.01) C07C 11/02 (2006.01) C07C 15/02 (2006.01)

Patent

CA 2012990

A novel solid phosphoric acid catalyst of controlled porosity and process for using this catalyst is disclosed. The catalyst com- prises a combination of solid phosphoric acid and a refractory oxide binder to make a porous catalyst system having 25.0 volume percent or less of the total catalyst pore volume consisting of pores having a diameter of 10,000 Angstroms (.ANG.) or greater. An improvement in catalyst stability is observed when such a catalyst is utilized in a hydrocarbon conversion process of the type that have traditionally used solid phos- phoric acid catalysts such as catalytic condensation of olefins to make a desired oligomer or alkylation of aromatic hydrocarbon with an olefin-acting agent.

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