Precipitation polymerization of copolymers of a vinyl lactam...

C - Chemistry – Metallurgy – 08 – F

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402/297, 402/477

C08F 2/06 (2006.01) C08F 220/04 (2006.01) C08F 222/02 (2006.01) C08F 226/06 (2006.01)

Patent

CA 2014022

PRECIPITATION POLYMERIZATION OF COPOLYMERS OF A VINYL LACTAM AND A POLYMERIZABLE CARBOXYLIC ACID IN AN ALIPHATIC HYDROCARBON SOLVENT ABSTRACT OF THE DISCLOSURE What is described herein is a precipitation polymerization process and copolymer products produced thereby. Polymerization is carried out in a reaction mixture of a vinyl lactam, e.g. vinyl pyrrolidone or vinyl caprolactam, and a polymerizable carboxylic acid, e.g. acrylic acid or methacrylic acid, in the presence of a polymerization initiator, in an aliphatic hydrocarbon solvent, particularly, a C3-C10 saturated hydrocarbon, which is branched or unbranched, cyclic or acylic and preferably, is heptane or cyclohexane.

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