Precursor of a low thermal stress polyimide and a...

C - Chemistry – Metallurgy – 08 – G

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402/221, 96/252,

C08G 73/10 (2006.01) C08G 73/12 (2006.01) G03F 7/031 (2006.01) G03F 7/038 (2006.01) G03F 7/26 (2006.01) H05K 1/00 (2006.01) H05K 1/03 (2006.01) H05K 3/46 (2006.01)

Patent

CA 1335817

Disclosed is a polyimide precursor comprising a specific polyamic acid ester, polyamic amide or polyamic acid salt structure derived from a tetracarboxylic acid compound and a diamine compound, which can be converted by heating to a polyimide having low thermal stress. By blending a specific form of this novel polyimide precursor which has an ethylenic double bond, with a photopolymerization initiator, an excellent photopolymerizable composition can be obtained. Not only this precursor but also the crosslinked precursor obtained by the photopolymerization of the photopolymerizable composition can be converted by heating to a polyimide resin which has low thermal expansion coefficient, high heat resistance, excellent mechanical properties and satisfactory adhesion to a substrate. Hence, the precursor and the photopolymerizable composition can advantageously be utilized in the production of electrical and electronic components.

609189

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