Preparation of 2,3-dihydro-2,2-dimethyl-7- hydroxy benzofuran

C - Chemistry – Metallurgy – 07 – C

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260/618, 260/367

C07C 39/19 (2006.01) C07C 37/00 (2006.01) C07C 37/055 (2006.01) C07D 307/86 (2006.01)

Patent

CA 1150289

A B S T R A C T 2,3-Dihydro-2,2-dimethyl-7-hydroxybenzofuran, a compound useful inter alia for the preparation of the known insecticide Carbofuran (i.e. 2,3-dihydro-2,2- dimethylbenzofuranyl methylcarbamate), is prepared by heating 3-isobutenyl-1,2-dihydroxybenzene, optionally in conjunction with 3-methallyl-1,2-dihydroxybenzene, in the presence of a sulphonic acid catalyst.

356343

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