Preparation of 2-halo-1-alkenes and acrylate esters from...

Details Preparation of 2-halo-1-alkenes and acrylate esters from... Preparation of 2-halo-1-alkenes and acrylate esters from...

C - Chemistry, Metallurgy

07

C

260/654, 260/661

C07C 17/08 (2006.01) C07C 21/02 (2006.01)

Patent

CA 1236120

-18- ABSTRACT A 2-halo-1-alkene (such as 2-chloro-1-pro- pene) is prepared by contacting together, in the pres- ence of a catalyst (such as alumina), (a) a 1,2-diene (such as propadiene) and/or a 1-alkyne (such as pro- pyne), with (b) a hydrogen halide (such as HCl); in the presence of at least 1,000 ppm water. The process of the invention provides unexpected selectivity for the desired product. 28,803A-F -18-

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