Preparation of 2-propylheptanol and other alcohols

C - Chemistry – Metallurgy – 07 – C

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260/637, 260/568

C07C 31/125 (2006.01) C07C 47/19 (2006.01) C07C 47/263 (2006.01)

Patent

CA 1257294

PREPARATION OF 2-PROPYLHEPTANOL AND OTHER ALCOHOLS ABSTRACT A preparation of a plasticizer alcohol, consisting of predominantly 2-propylheptanol, from linear butenes is described in which oxo product of the butenes is aldoled to condense n-pentaldehyde therein with very little cross-aldolization followed by hydrogenation to obtain the 2-propylheptanol with very small 2-propyl- 4-methyl hexanol content. The alcohol product as phthalate ester has excellent plasticizer properties. Also processes are described for converting other olefins to alcohols by oxo, aldol and hydrogenation reactions, with particular attention to converting hexenes obtained by propylene dimerization to C14 alcohols suitable for preparation of detergents.

401866

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