Preparation of 4-pentenenitrile by isomerization

C - Chemistry – Metallurgy – 07 – C

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C07C 253/30 (2006.01) B01J 27/22 (2006.01) B01J 29/12 (2006.01) B01J 29/22 (2006.01) B01J 39/00 (2006.01) C07B 35/08 (2006.01) C07C 255/07 (2006.01) B01J 29/44 (2006.01)

Patent

CA 1331628

TITLE Preparation of 4-pentenenitrile By Isomerization Abstract A process is disclosed for the preparation of 4- pentenenitrile by isomerization of 3-pentenenitrile. In the process, 3-pentenenitrile is contacted with a heterogeneous catalyst selected for the group consisting of acid ion-exchange resins promoted with at least one group 8 noble metal in an oxidation state of at least +2, amorphous silica aluminates promoted with at least one group 8 noble metal, charcoal promoted with at least one group 8 noble metal, acid zeolites promoted with at least one group 8 noble metal, and perfluorinated ion-exchange polymers.

568217

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