Preparation of alkyl silanes

C - Chemistry – Metallurgy – 07 – F

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260/448.8

C07F 7/08 (2006.01)

Patent

CA 1320738

PREPARATION OF ARYL SILANES Abstract of the Disclosure Olefins and metal aluminum tetralkyls react with alkylhalosilanes to yield mixtures of tetralkyl silanes which may be employed as functional fluids. For example, decene-1 and sodium aluminum tetraoctyl, NaAl(C8H17)4, react with methyl trichlorosilane. The mole ratio of sodium aluminum tetralkyl to halosilane is from 0.75:1.0, to 1:1, and the ratio of olefin to the metal aluminate is selected to confer in the product mixture, the desired concentra- tion of alkyl radicals derived from the olefin.

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