Preparation of amine alanes

C - Chemistry – Metallurgy – 07 – F

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260/433

C07F 5/06 (2006.01)

Patent

CA 1276941

ABSTRACT Process for the preparation of an amine alane, the process comprising reacting: (a) an alkali metal aluminum tetrahydride having the formula MAlH4, wherein M is an alkali metal selected from the class consisting of lithium, sodium and potassium; (b) a hydrogen halide; and (c) a complexing tertiary amine. In this process, NaAlH4, HCl and (C2H5)3N are preferred reactants. These materials are useful as chemical inter- mediates. For example, they can be reacted with a silicon halide such as SiC14 or SiF4 to produce silane.

551589

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