Preparation of amines from olefins using certain transition...

C - Chemistry – Metallurgy – 07 – D

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260/609, 260/601

C07D 295/023 (2006.01) C07C 209/60 (2006.01)

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CA 1176661

ABSTRACT Aliphatic and aromatic amines are produced by reacting an olefin with either ammonia or a primary or secondary amine in the presence of a catalytic amount of a ruthenium or iron compound catalyst, either dissolved in an inert solvent or in the absence of a solvent at a temperature of 100 to 250°C and a pressure of from atmospheric to 12,000 psig. Amines have many important commercial uses such as inter- mediates in the manufacture of rubber products, pharmaceuticals, insecticides, dyestuffs, textile finishing agents, etc.

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