Preparation of chiral 1-benzyl-1,2,3,4-...

Details Preparation of chiral 1-benzyl-1,2,3,4-... Preparation of chiral 1-benzyl-1,2,3,4-...

C - Chemistry, Metallurgy

07

D

260/286, 260/277

C07D 217/20 (2006.01) C07D 489/00 (2006.01)

Patent

CA 1183134

ABSTRACT OF THE DISCLOSURE In a short total synthesis of morphinan compounds, derivatives of 1-benzyl-1,2,3,4-tetrahydroisoquinoline are produced. Certain of these compounds, although highly aromatic and functionalized, can be optically resolved. The optically active enantiomers can serve as important intermediates for both natural and unnatural opioids.

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