C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/703
C07C 2/38 (2006.01) C07C 2/74 (2006.01) C07C 11/02 (2006.01)
Patent
CA 2003568
\ T 322 FF ABSTRACT PREPARATION OF CONJUGATED DIENES A process for the preparation of a compound of general formula Image (I) in which R1 represents a hydrogen atom or a methyl group, one of R2 and R3 represents a hydrogen atom and the other of R2 and R3 is the same as R1, which comprises reacting a compound of general formula R1-CH=C=CH2 (II) with a salt of formic acid in the presence of a catalyst system comprising a palladium salt and a phosphorus compound of general formula P(OX)n(X)3-n (III) in which n is 0,1,2 or 3 and each X independently represents an alkyl, alkenyl, aryl, aralkyl, alkaryl or cycloalkyl group, and recovering the desired compound of formula (I). PS11010
Cornelis Jacob
Goodall Brian L.
Sar Van D.
Terlouw Willem
Shell Canada Limited
Smart & Biggar
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