Preparation of emulsifier-free aqueous polymer emulsions

C - Chemistry – Metallurgy – 08 – F

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C08F 2/22 (2006.01) C08F 220/06 (2006.01) C08F 222/02 (2006.01) C09D 5/02 (2006.01) C09J 9/00 (2006.01)

Patent

CA 2169129

An aqueous polymer emulsion obtainable by free radical polymerization of monomers in aqueous emulsion in the presence of a polymeric protective colloid contains, as components, - from 5 to 50% by weight of at least one ethylenically unsaturated monomer having at least one acid or acid anhydride group (monomers I), - from 0.1 to 80% by weight of at least one (meth)acrylate of an aliphatic alcohol of at least 10 carbon atoms (monomers II), - from 0 to 94.9% by weight of main monomers selected from the group consisting of C1-C8-alkyl (meth)acrylates, vinyl esters of carboxylic acids of up to 20 carbon atoms, vinyl aromatics of up to 20 carbon atoms, ethylenically unsaturated nitrites, vinyl halides and aliphatic hydrocarbons having 2 to 8 carbon atoms and 1 or 2 double bonds (monomers III) and - from 0 to 60% by weight of further monomers (monomers IV), the stated weights being based on the polymeric protective colloid.

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