Preparation of finely divided, gel-like, water-swellable...

C - Chemistry – Metallurgy – 08 – F

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402/397, 402/404

C08F 2/04 (2006.01) A61L 15/60 (2006.01) C08F 2/10 (2006.01)

Patent

CA 2004331

O.Z. 0050/4043 Abstract of the Disclosure: Finely divided, gel-like, water-swellable copolymers are prepared by copolymerizing (a) 100 parts by weight of water-soluble, monoethylen- ically unsaturated monomers, (b) from 0.01 to 5 parts by weight of monomers contain- ing two or more ethylenically unsaturated double bonds and (c) from 0 to 20 parts by weight of water-insoluble, monoethylenically unsaturated monomers in 20-80% strength by weight aqueous solution in the presence of a polymerization initiator and from 0.1 to 10% by weight, based on the monomers used in the co- polymerization, of a surfactant, by a process in which the monomers are copolymerized in the presence of in- itially from 0 to 50% by weight of the amount of sur- factant to a conversion of not less than 60%, the remaining amount of surfactant is then added to the reaction mixture and the copolymerization is completed and the resulting gel particles dried.

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