Preparation of homopolymers and copolymers of ethylene by...

C - Chemistry – Metallurgy – 08 – F

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402/565

C08F 10/00 (2006.01) C08F 4/64 (2006.01)

Patent

CA 1276384

Abstract of the Disclosure: Ethylene is polymerized us ing a Ziegler catalyst system consisting of (1) a titanium catalyst component and (2) an aluminum catalyst component, the component (1) used being the product (VI) which is obtained by a method in which (1.1) first (1.1.1) a car- rier (I) and (1.1.2) a solution (II) of (IIa) a solvent, (IIb) a titanium trichloride and (IIc) magnesium chloride are combined with formation of a dispersion (III) and the latter is evaporated down with formation of an inter- mediate (IV), and (1.2) then (1.2.2) the intermediate (IV) obtained from (1.1), and (1.2.2) an aluminum component (V) consisting of (1.2.2.1) a complex of a certain oxacyclo- alkane and a certain aluminum compound and (1.2.2.2) if necessary, a certain free aluminum compound are combined, the resulting product (VI) being the catalyst component (1). In this process, a component (1) is employed which has been prepared using, in (1.1) under (1.1.2), a solu- tion (II) which (i) contains a ketone as (IIa) and (ii) additionally contains (IId) a certain low molecular weight polymeric compound.

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