Preparation of insoluble polymer powders which are only...

C - Chemistry – Metallurgy – 08 – F

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402/403, 402/405

C08F 26/10 (2006.01) C08F 226/10 (2006.01)

Patent

CA 1241798

Abstract of the Disclosure: Insoluble polymer powders which are only slightly swellable and are based on N-vinyl- pyrrolidone are prepared by polymerization of N-vinyl- pyrrolidone or a mixture of this with copolymerizable monomers and from 0.1 to 10% by weight, based on the total amount of monomers, of a crosslinking agent in 2 powder bed in the presence of a heat-transfer medium, which is inert to the reactants, and in the absence of oxygen and polymerization initiators, at from 90 to 220°C, while maintaining the powder state, circulating the reaction mass and evaporating the heat-transfer medium from the polymerization zone. The resulting insoluble polymers which are only slightly swellable are used as adsorbents or formulation assistants for fertilizers and crop pro- tection agents.

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